Insertion of Ruthenium into an inorganic, cyclic biradicaloid
نویسندگان
چکیده
The reaction between [Ru 2 Cl ( my -Cl) (CO) 6 ] and the biradicaloid [P( -NTer)] proceeds under insertion of a Ru(II)Cl(CO) fragment into one P-N bond addition chloride to adjacent phosphorus center. Thereby an unprecedented ruthenacycle is obtained that was investigated by single crystal X-ray analysis, NMR IR spectroscopy DFT calculations. reactivity complex in halide-pseudo-halide exchange coordination were investigated.
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2022
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202200093